By Roy G.D. (ed.)

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Law of Princeton University to be extremely useful for the creation of microexplosions for 23 fuel droplet atomization. Cubane has an extremely high-strain energy around 166 kcal/mole and ring opening releases a substantial amount of this strain energy. 1 SYNTHESIS OF CUBYL SYSTEMS Synthesis of 1,4-Bis-Azidomethylcubane This compound (4) was synthesized via the route shown in Fig. 1. Compound 4 was prepared in overall 35% yield and the synthesis could be scaled to gram quantities in polyunsaturated cubane considered in the next section.

Roy and P. Strykowski. Minneapolis, MN. SECTION ONE ADVANCED FUEL SYNTHESIS AND CHARACTERIZATION Chapter 2 HIGH-ENERGY, HIGH-DENSITY, POLYCYCLIC HYDROCARBONS AND AZIDO DERIVATIVES R. M. Moriarty Efforts towards the synthesis of strained polycyclic hydrocarbons have been described. These compounds are of interest as fuels and fuel additives for advancedpropulsion. Chemistry has been devised for the attachment of azido functionality to the strained hydrocarbon nucleus. Highly unsaturated substituted cubanes have been synthesized.

Supersonic combustion phenomena for future hypersonic vehicles pose the difficult issue on mixing enhancement as efficient highspeed combustion is required in compact combustors with very short residence times. New combustion concepts are emerging (Fig. 2); one based on countercurrent shear offers promise [9]. A current project addresses the utilization of this concept in a practical combustor. Exploration of new avenues to reduce emissions to comply with environmental regulations has always been a priority in the past decade.

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