By Karen I. Goldberg and Alan S. Goldman (Eds.)

Content material: 1. Organometallic C-H bond activation : an creation / Alan S. Goldman and Karen I. Goldberg -- 2. C-H bond activation by way of iridium and rhodium complexes : catalytic hydrogen-deuterium trade and C-C bond-forming reactions / Steven R. Klei, Kian L. Tan, Jeffrey T. Golden, Cathleen M. Yung, Reema okay. Thalji, Kateri A. Ahrendt, Jonathan A. Ellman, T. Don Tilley and Robert G. Bergman

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Journal of Physical Chemistry 1956, 60, 280. (b) Halpern, J. Journal of Physical Chemistry 1959, 63, 398. ; DiLuzio, J. W. J. Am. Chem. Soc. 1962, 84, 679. (a) Vaska, L . Acc. Chem. Res. 1968, 1, 335. F. Ann. Ν. Y. Acad. Sci. 1971, 172, 546. (a) Kubas, G . ; Ryan, R. ; Swanson, B . ; Vergamini, P. ; Wasserman, H . J. J. Am. Chem. Soc. 1984, 106, 451. , J. Acc. Chem. Res. 1998, 21, 120. ; Davidson, J. M. J. Chem. Soc. 1965, 843. Young, J. ; Osborn, J. ; Jardine, F. H . ; Wilkinson, G . Chem. Comm.

Carbon-Hydrogen Bond Activation at Methyliridium(III) Centers Several years ago we (and simultaneously, Hoyano and Graham) discovered one o f the first " C - H activation" reactions that converts alkanes into isolable metal complexes (eq 1) (5-7). The important step in this process involves the generation of an exceedingly reactive iridium, rhodium (8,9) or rhenium (10) fragment, in formal oxidation state +1, which undergoes an oxidative addition reaction leading to a metal (+3) product containing a new metal-carbon and metal-hydrogen bond.

Baxter, S. M . ; Wolczanski, P. T. J. Am. Chem. Soc. 1988, 110, 8731. 149. Walsh, P. ; Hollander, F. ; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729. 150. ; Pamplin, C. ; Patrick, B. ; Bau, R. J. Am. Chem. Soc. 2003, 125, 7035. 151. (a) Del Rossi, K. ; Wayland, Β. B. J. Am. Chem. Soc. 1985, 107, 7941. (b) Del Rossi, K. ; Wayland, Β. B. Chem. Comm. 1986, 1653. (c) Sherry, A. ; Wayland, Β. B. J. Am. Chem. Soc. 1990, 112, 1259. (d) Wayland, B. ; Sherry, A. E. J. Am. Chem. Soc. 1991, 113, 5305.

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